I thought it was understood that James Bond orders his drink incorrectly BECAUSE he was uncultured and a "blunt instrument" trying to play the part of a sophisticated gentleman. It was his one "tell" to the character he had created to pass in and out of high society where his potential targets most frequented.
I always loved that about his order, he really knows how to jack up a good martini.
I would add Groundhog Day's Sweet Vermouth with a twist and a toast to World Peace.
I'm surprised Ron Burgundy's Scotch, Scotch, Scotch didn't beat out Ron Swanson but I'll take Scotch anyway I can.
As a final note I thought I ask; who's the Hipster on staff that remembered the line from Blue Velvet?